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14985-26-3

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14985-26-3 Usage

General Description

The chemical compound (2S,3S)-2-(4-nitrophenyl)-3-phenyloxirane, also known as 2-(4-nitrophenyl)-3-phenyl-oxirane, is a chiral epoxide with the molecular formula C15H11NO3. It is a stereoisomer with two chiral centers and is commonly used as a building block in organic synthesis. (2S,3S)-2-(4-nitrophenyl)-3-phenyloxirane contains a 4-nitrophenyl group and a phenyl group attached to an oxirane ring, which imparts reactivity and stability to the molecule. It is often used as an intermediate in the synthesis of pharmaceuticals and agrochemicals, as well as in materials science and other research applications.

Check Digit Verification of cas no

The CAS Registry Mumber 14985-26-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,9,8 and 5 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 14985-26:
(7*1)+(6*4)+(5*9)+(4*8)+(3*5)+(2*2)+(1*6)=133
133 % 10 = 3
So 14985-26-3 is a valid CAS Registry Number.

14985-26-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name trans-2-(4-nitrophenyl)-3-phenyloxirane

1.2 Other means of identification

Product number -
Other names (2R,3R)-2-(4-nitrophenyl)-3-phenyl oxirane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14985-26-3 SDS

14985-26-3Relevant articles and documents

Radical-mediated aerobic oxidation of substituted styrenes and stilbenes

Aman, Hasil,Chiu, Wei-Hua,Chuang, Gary Jing,Liu, Pin-Heng

supporting information, p. 20103 - 20106 (2021/12/02)

A 2,2-azobis(isobutyronitrile)-catalyzed oxidative cleavage of alkenes with molecular oxygen as the oxidant was described. Carbonyl compounds and oxiranes were obtained in moderate yield under mild conditions. This study provided useful insights into the mechanism of aerobic oxidative cleavage of alkenes.

One-pot synthesis of epoxides from benzyl alcohols and aldehydes

Alfonzo, Edwin,Mendoza, Jesse W.L.,Beeler, Aaron B.

supporting information, p. 2308 - 2312 (2018/09/14)

A one-pot synthesis of epoxides from commercially available benzyl alcohols and aldehydes is described. The reaction proceeds through in situ generation of sulfonium salts from benzyl alcohols and their subsequent deprotonation for use in Corey–Chaykovsky epoxidation of aldehydes. The generality of the method is exemplified by the synthesis of 34 epoxides that were made from an array of electronically and sterically varied alcohols and aldehydes.

The B(C6F5)3-Catalyzed Tandem Meinwald Rearrangement-Reductive Amination

Tiddens, Martine R.,Klein Gebbink, Robertus J. M.,Otte, Matthias

supporting information, p. 3714 - 3717 (2016/08/16)

A system of three coupled catalytic cycles enabling the one-pot transformation of epoxides to amines via Meinwald rearrangement, imine condensation, and imine reduction is described. This assisted tandem catalysis is catalyzed by B(C6F5)3 resulting in the first tandem Meinwald rearrangement-reductive amination protocol. The reaction proceeds in nondried solvents and yields β-functionalized amines. In particular, β-diarylamines are obtained in high yields.

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