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149869-56-7

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149869-56-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 149869-56-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,9,8,6 and 9 respectively; the second part has 2 digits, 5 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 149869-56:
(8*1)+(7*4)+(6*9)+(5*8)+(4*6)+(3*9)+(2*5)+(1*6)=197
197 % 10 = 7
So 149869-56-7 is a valid CAS Registry Number.

149869-56-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name carbanide,chloropalladium(1+),triphenylphosphane

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:149869-56-7 SDS

149869-56-7Upstream product

149869-56-7Relevant articles and documents

Cationic methyl-palladium(II) complexes containing bidentate N ^ O and P ^ O ligands and a tridentate P ^ O ^ N ligand: Synthesis, carbonylation and catalytic applications in the copolymerisation of carbon monoxide and ethene

Britovsek, George J.P.,Cavell, Kingsley J.,Green, Melinda J.,Gerhards, Frank,Skelton, Brian W.,White, Allan H.

, p. 201 - 212 (2007/10/03)

Cationic methyl-palladium complexes, containing chelating N-O, P-O and P-O-N ligands, of the type {[PdMe(Y-O)L]BF4} and {[PdMe(P-O-N)]BF4} [Y-O = methylpicolinate, L = PPh3, Ph2PCH2COOEt; Y-O = Ph2PCH2COOEt, L = PPh3, 2,6-lutidine; P-O-N = diphenylphosphine-acetic acid-methyl-2-pyridylester (Ph2PCH2CO2CH2(NC5H4-2))] have been synthesized. The crystal structure of the complex {[PdMe(N-O)PPh3]BF4} indicates distorted square-planar coordination around the palladium centre. The bite angle of the methylpicolinate ligand is small [74.8(4)°] and the Pd-N [2.141(9)A] and Pd-O [2.180(7) A] bonds to the ligand are somewhat elongated. The complexes react readily with CO to give the corresponding acyl complexes, and with the exception of {[PdMe(N-O)Ph2PCH2COOEt]BF4} catalyse the reaction between CO and ethene at room temperature to give polyketone.

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