149883-63-6

Upstream product

• 14168-65-1 mannosan 
• 824-94-2 p-methoxybenzyl chloride 
• 144152-51-2 1,6-anhydro-4-O-benzoyl-2-O-(p-methoxybenzyl)-β-D-arabino-hexopyran-3-ulose 
• 14440-51-8 1,6-anhydro-2,3-O-isopropylidene-β-D-mannopyranose 
• 7225-53-8 (-)-1,6-anhydro-4-O-benzoyl-β-D-mannopyranose 
• 131940-20-0 (-)-1,6-anhydro-4-O-benzoyl-2,3-isopropylidene-β-D-mannopyranose 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 149883-62-5 (1R,2S,4S,5R)-3-[2-Hydroxy-eth-(E)-ylidene]-4-(4-methoxy-benzyloxy)-6,8-dioxa-bicyclo[3.2.1]octan-2-ol 

Downstream Products

• 144152-55-6 2'-methyl-(1,6-anhydro-3-deoxy-2-O-(p-methoxybenzyl)-3-C-vinyl-β-D-altropyranosido)-<3,4:4',5'>-Δ^2'-oxazoline 
• 144152-54-5 (1R,2S,6R,7S,8R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-1-iodo-ethyl]-7-(4-methoxy-benzyloxy)-4-trichloromethyl-3,9,11-trioxa-5-aza-tricyclo[6.2.1.0^2,6]undec-4-ene 

Relevant academic research and scientific papers

NOVEL REACTIONS OF CARBOHYDRATES DISCOVERED EN ROUTE TO NATURAL PRODUCTS

An approach to the synthesis of tetrodotoxin is described in which two key reactions are used to establish the densely functionalized carbocyclic ring.The -bicyclic framework of 1,6-anhydro mannopyranose serves as the the template, and in the first