1499-65-6

Basic information

• Product Name: (2RS,3RS)-3-methyl-hexan-2-ol
• CAS NO: 1499-65-6
• Molecular Weight: 116.203
• Mol File: 1499-65-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2RS,3RS)-3-methyl-hexan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2RS,3RS)-3-methyl-hexan-2-ol(1499-65-6)
• EPA Substance Registry System: (2RS,3RS)-3-methyl-hexan-2-ol(1499-65-6)

Safety Data

• Hazardous Substances Data: 1499-65-6(Hazardous Substances Data)

Upstream product

• 25409-10-3 3-propyl-3-buten-2-one 
• 591-78-6 n-hexan-2-one 
• 73153-94-3 (R)-2-Ethyl-1-methylbutylamin 
• 1499-66-7 (2RS,3SR)-3-methyl-hex-5-en-2-ol 
• 1499-66-7 3-methylhex-5-en-2-ol 
• 21490-63-1 2,3-trans-epoxybutane 
• 1730-25-2 allylmagnesium bromide 
• 4907-44-2 di-n-propylmagnesium 
• 925669-95-0 2,3-cis-epoxybutane 

Relevant articles and documents

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Stereochemistry of Aliphatic Carbocations, 13. Protonated Cyclopropanes as Intermediates in 1,2-Alkyl Shifts

The nitrous acid deamination of 2-ethyl-1-methylbutylamine (10), 1,2-diethylbutylamine (35), and 2-ethyl-1-methylpentylamine (43) has been studied with respect to 1,2-alkyl shifts.Optically active and deuterated amines were employed whenever possible.The structure, configuration, and deuterium distribution of various products (e. g. 16 from 10, 40 and 48 from 35, 56 from 43) are most reasonably explained in terms of alkyl-bridged intermediates (corner-protonated cyclopropanes) which isomerize via proton shifts from corner to corner.The alternative interconversion of open ions via 1,3-H shifts is incompatible with our experimental results.