149901-41-7Relevant academic research and scientific papers
Syntheses and Structures of Transition-Metal Complexes of Mesoionic Olate, Thiolate, Selenolate, and Cyclopentadienide
Araki, Shuki,Butsugan, Yasuo
, p. 1157 - 1160 (2007/10/02)
The dicarbonyl(η-cyclopentadienyl)iron(II) complex 5 of 1,3-diphenyltetrazolium-5-olate (4) and the pentacarbonylmolybdenum(0) complexes 7, 11, and 9 of 1,3-diphenyltetrazolium-5-thiolate (6), -5-selenolate (10), and 5-methyl-1,4-diphenyl-1,2,4-triazolium-3-thiolate (8) as well as tricarbonylchromium(0) complex 13 and -molybdenum(0) complex 14 of 1,3-diphenyltetrazolium-5-cyclopentadienide (12) have been prepared.Their physicochemical properties are discussed on the basis of spectroscopic properties.Key Words: Mesoionic compounds / Transition metal complexes / Tetrazolium-4-olate, -4-thiolate, -4-selenolate-, 4-cyclopentadienide, complexes with molybdenum or chromium carbonyls / 1,2,4-Triazolium-3-thiolate, complex with pentacarbonylmolybdenum
