1499076-64-0

Basic information

• Product Name: 6a-fluoro-7,7-dimethyl-5-tosyl-6,6a,7,11b-tetrahydro-5H-indeno[2,1-c]quinoline
• CAS NO: 1499076-64-0
• Molecular Weight: 421.535
• Mol File: 1499076-64-0.mol

Chemical Properties

• CAS DataBase Reference: 6a-fluoro-7,7-dimethyl-5-tosyl-6,6a,7,11b-tetrahydro-5H-indeno[2,1-c]quinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 6a-fluoro-7,7-dimethyl-5-tosyl-6,6a,7,11b-tetrahydro-5H-indeno[2,1-c]quinoline(1499076-64-0)
• EPA Substance Registry System: 6a-fluoro-7,7-dimethyl-5-tosyl-6,6a,7,11b-tetrahydro-5H-indeno[2,1-c]quinoline(1499076-64-0)

Safety Data

• Hazardous Substances Data: 1499076-64-0(Hazardous Substances Data)

Upstream product

• 1499076-71-9 N-((1,1-dimethyl-1H-inden-2-yl)methyl)-4-methyl-N-phenylbenzenesulfonamide 

Relevant articles and documents

CHIRAL FLUORINATING REAGENTS

This invention relates to fluorinating agents and, more particularly, to chiral non-racemic fluorinating agents useful for enantioselective fluorination, as well as to their synthesis and use and other subject matter. The fluorinating agents are based on a substituted 1,4-diazabicyclo[2.2.2]octane (DABCO) skeleton and provide electrophillic fluorine enantioselectively.

Asymmetric electrophilic fluorocyclization with carbon nucleophiles

Twist of 'F'ate: Various helical-shaped fluorinated tetracyclic molecules were prepared by fluorocarbocyclization of prochiral alkenes. The development of a new class of chiral Selectfluor (1) proved instrumental in developing an asymmetric variant of this transformation. These novel chiral N-F reagents are readily accessible by fluorine transfer from shelf-stable N-fluoropyridinium salts. Copyright