1499076-69-5Relevant articles and documents
Asymmetric electrophilic fluorocyclization with carbon nucleophiles
Wolstenhulme, Jamie R.,Rosenqvist, Jessica,Lozano, Oscar,Ilupeju, John,Wurz, Nathalie,Engle, Keary M.,Pidgeon, George W.,Moore, Peter R.,Sandford, Graham,Gouverneur, Veronique
, p. 9796 - 9800 (2013/09/23)
Twist of 'F'ate: Various helical-shaped fluorinated tetracyclic molecules were prepared by fluorocarbocyclization of prochiral alkenes. The development of a new class of chiral Selectfluor (1) proved instrumental in developing an asymmetric variant of this transformation. These novel chiral N-F reagents are readily accessible by fluorine transfer from shelf-stable N-fluoropyridinium salts. Copyright