1500083-06-6Relevant articles and documents
Total synthesis of ent-(-)-azonazine using a biomimetic direct oxidative cyclization and structural reassignment of natural product
Zhao, Ji-Chen,Yu, Shun-Ming,Qiu, Hai-Bo,Yao, Zhu-Jun
, p. 3197 - 3210 (2014/05/06)
A biomimetic approach has been investigated and developed for the total synthesis of azonazine, an unusual marine natural cyclopeptide containing a rigid transannular 10-membered ring. A hypervalent iodine-mediated direct oxidative cyclization was success
Biomimetic synthesis of ent -(-)-azonazine and stereochemical reassignment of natural product
Zhao, Ji-Chen,Yu, Shun-Ming,Liu, Yun,Yao, Zhu-Jun
supporting information, p. 4300 - 4303 (2013/09/24)
The first total synthesis of ent-(-)-azonazine has been accomplished using a hypervalent iodine-mediated biomimetic oxidative cyclization to construct the highly strained core. Based on the results from the completed synthesis, both the relative and absolute configurations of natural (+)-azonazine were revised.