150024-91-2Relevant academic research and scientific papers
A mild and highly efficient laccase-mediator system for aerobic oxidation of alcohols
Zhu, Chenjie,Zhang, Zhi,Ding, Weiwei,Xie, Jingjing,Chen, Yong,Wu, Jinglan,Chen, Xiaochun,Ying, Hanjie
supporting information, p. 1131 - 1138 (2014/03/21)
With the aid of the highly active nitroxyl radical AZADO (2-azaadamantane N-oxyl), a simple method for the aerobic catalytic oxidation of alcohols is presented. The oxidations could typically proceed under practical ambient conditions (room temperature, air atmosphere, no moisture effect, metal-free, etc.) with a broad generality of the alcohol substrates, and especially for the oxidation of complex and highly functionalized alcohols. An ionic mechanism is proposed for the present system.
