150041-97-7Relevant academic research and scientific papers
Syntheses of 1,2-diamidobenzene complexes of molybdenum. Crystal structure of the complex cis-dicarbonyl 1,2-diamidobenzenebis(triphenylphosphine)molybdenum (CO)2(PPh3)2>
Anillo, Adela,Obeso-Rosete, Ricardo,Lanfranchi, Maurizio,Tiripicchio, Antonio
, p. 71 - 75 (2007/10/02)
The complex (1) is obtained from , 1,2-(NH2)2C6H4 and KOH dissolved in a mixture of tetrahydrofuran and water; its X-ray structure and properties are described.Substitution derivatives of this complex are obtained by reaction of 1 with P donors to give (L = PEt3 (2), P(OEt)3 (3)> and (4) , and their spectroscopic properties are reported.Attempted reactions of 1 with CO or dppm were unsuccessful and the starting complex were recovered unchanged.
