150096-40-5Relevant articles and documents
A bridge linking and its application of metal complexes
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Paragraph 0076, (2017/02/23)
The invention discloses a bridged metallocene complex, which is characterized by having a structural formula shown as the following A1, A2, A3 or A4. The invention also discloses a preparation method of ethylene propylene rubber. The ethylene propylene ru
Synthesis and molecular structures of zirconium and hafnium complexes bearing dimethylsilandiyl-bis-2,4,6-trimethylindenyl and dimethylsilandiyl-bis- 2-methyl-4,6-diisopropylindenyl ligands
Izmer, Vyacheslav V.,Sorokin, Denis A.,Kuz'Mina, Lyudmila G.,Churakov, Andrei V.,Howard, Judith A.K.,Voskoboynikov, Alexander Z.
, p. 1067 - 1079 (2007/10/03)
Zirconium and hafnium ansa-complexes containing 2,4,6-trialkyl-substituted indenyl fragments were synthesized and unambiguously characterized. Mixtures of rac- and meso-Me2Si(2-Me-4,6-R2C9H 3-η5)2MCl2, where R = Me, i-Pr and M = Zr, Hf, were obtained by a treatment of MCl4 by dilithium salts of the respective bis(2,4,6-trialkylindenyl)dimethylsilanes in toluene. Alternatively, better yields of the same complexes can be obtained by the reaction between metal tetrachlorides and indenyl-tin derivatives gave the desired ansa-metallocenes. All rac- and meso-complexes of Zr and Hf were isolated in an analytically pure form, and six of these ansa-metallocenes were characterized by X-ray crystal structure analysis.
Process for the preparation of substituted indenes and their use as ligand systems for metallocene catalysts
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, (2008/06/13)
The invention relates to a process for the preparation of a compound of the formula IV or IVa STR1 in which R1 -R5 are preferably hydrogen or alkyl, which comprises reacting a compound I STR2 with a compound II STR3 in which X1 and X2 are preferably halogen, to give the corresponding indanones, which are converted into the compounds IV and IVa by reduction and dehydration. The compounds IV and IVa are important intermediate products for the preparation of chiral metallocene complexes which are suitable catalyst components for olefin polymerization.