150163-19-2Relevant academic research and scientific papers
Direct Free-Radical Substitutions on Allyl and Vinyl Halides Using Alkyl Halides/Hexabutylditin
Huval, Chad C.,Singleton, Daniel A.
, p. 3041 - 3042 (2007/10/02)
Allyl and vinyl halides are excellent acceptors for tin-mediated substitutions by alkyl radicals generated from alkyl halides.
A STEREOCONTROLLED SYNTHESIS OF 2-METHYL-ALKENENITRILES FROM C-METHYL-C, N-BIS(TRIMETHYLSILYL)KETENIMINE AND ALDEHYDES
Okada, Hisashi,Matsuda, Isamu,Izumi, Yusuke
, p. 97 - 100 (2007/10/02)
A stereocontrolled synthesis of 2-methyl-2-alkenenitriles is achieved via the diastereoselective aldol type reaction of C-methyl-C,N-bis(trimethylsilyl)ketenimine with aldehydes in the presence of a mixture of TiCl4 and Ti(O-iPr)4.
