150192-86-2Relevant academic research and scientific papers
PHOTOCHEMISTRY OF HOMOCONJUGATED KETONES: 2-(CARBOMETHOXY)SPIROUNDECA-1,3-DIEN-7-ONE
Oren, Jakob,Schleifer, Leah,Shmueli, Uri,Fuchs, Benzion
, p. 981 - 984 (1984)
The direct and sensitized irradiation of the title comound (2c) was studied with particular attention to its oxa-di-?-methane rearrangement, the product of which is of notable structural and synthetic interest.X-ray diffraction data of the final product (
67. Homoconjugated Ketones with Extended Unsaturation: Wavelength-Selective, Regioselective, Diastereoselective, and Enantiospecific Photochemical Transformations of Methyl 7-Oxospiroundeca-1,3-and -2,4-diene-2-carboxylate
Oren, Jakob,Vardi, Michaela,Viskin, Rossana,Abramson, Sarah,Fuchs, Benzion
, p. 1182 - 1193 (2007/10/02)
The title molecules were shown to photorearrange with remarkable selectivity.Wavelength variation steers the rearrangement modes, of which the -acyl shift was found to be largely regioselective, diastereoselective, and enantiospecific.Chemical interc
