150205-61-1Relevant academic research and scientific papers
Photochemistry of 2-(methoxycarbonyl)phenyl azide in solution at room temperature: A time-resolved infrared study
Sun, Xue-Zhong,Virrels, Ian G.,George, Michael W.,Tomioka, Hideo
, p. 1089 - 1090 (1996)
Time-resolved infrared studies of intermediates generated by photolysis of the title azide in solution at room temperature demonstrated that 3-(methoxycarbonyl)azacycloheptatetraene was the sole intermediate at least in the μs time scale, which is in sharp contrast with that observed in the photolysis in argon matrix at 10 K. Substituent effects on the reactivity of the dehydroazepine toward diethylamine are also discussed.
Photochemistry of 2-(methoxycarbonyl)phenyl azide studied by matrix-isolation spectroscopy. A new slippery energy surface for phenylnitrene
Tomioka, Hideo,Ichikawa, Naoki,Komatsu, Kazunori
, p. 8621 - 8626 (1993)
Broad-band irradiation (λ > 350 nm) of 2-(methoxycarbonyl)phenyl azide (1) in Ar at 10 K monitored by IR and UV-vis spectroscopy resulted in the formation of at least five major products, all of which were shown to be photointerconvertible under these con
