150255-45-1

Basic information

• Product Name: (-)-(S)-2-(2-fluoro-phenyl)-4-methyl-4,5-dihydro-oxazole
• Synonyms: (-)-(S)-2-(2-fluoro-phenyl)-4-methyl-4,5-dihydro-oxazole
• CAS NO: 150255-45-1
• Molecular Weight: 179.194
• Mol File: 150255-45-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (-)-(S)-2-(2-fluoro-phenyl)-4-methyl-4,5-dihydro-oxazole(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(S)-2-(2-fluoro-phenyl)-4-methyl-4,5-dihydro-oxazole(150255-45-1)
• EPA Substance Registry System: (-)-(S)-2-(2-fluoro-phenyl)-4-methyl-4,5-dihydro-oxazole(150255-45-1)

Safety Data

• Hazardous Substances Data: 150255-45-1(Hazardous Substances Data)

Upstream product

• 393-52-2 2-Fluorobenzoyl chloride 
• 111904-32-6 (1'S)-2-fluoro-N-<1-(hydroxymethyl)ethyl>benzamide 
• 179116-96-2 (-)-(S)-N-(2-chloro-1-methyl-ethyl)-2-fluoro-benzamide 
• 2749-11-3 (S)-Alaninol 
• 394-47-8 2-fluorobenzonitrile 

Downstream Products

• 148461-12-5 (-)-(S)-2-(2-diphenylphosphino-phenyl)-4-methyl-4,5-dihydro-oxazole 

Relevant articles and documents

Asymmetric Palladium Catalysed Allylic Substitution Using Phosphorus Containing Oxazoline Ligands

A series of new phosphorus-containing oxazoline ligands has been developed.The use of these ligands for asymmetric palladium catalysed allylic substitution of 1,3-diphenylprop-2-enyl-1-acetate 12 with the sodium salt of dimethylmalonate has been achieved

Palladium-catalysed Asymmetric Allylic Substitution: a Ligand Design Incorporating Steric and Electronic Effects

Enantiomerically pure ligands containing a 4,5-dihydrooxazole moiety tethered to an auxiliary sulfur or phosphorus donor have been prepared.These ligands have been exploited for palladium-catalysed asymmetric allylic substitution, providing enantioselectivity in the catalytic reaction is discussed in terms of the steric and electronic influences provided by the ligand.