Cas 150266-91-4,cis-bromobis{((1,3-dioxane-2-yl)methyl)diphenylphosphane-P;O',P'}palladium(II) perchlorate

150266-91-4

Post Buying Request

Basic information

Product Name: cis-bromobis{((1,3-dioxane-2-yl)methyl)diphenylphosphane-P;O',P'}palladium(II) perchlorate
Synonyms:
CAS NO:150266-91-4
Molecular Formula:
Molecular Weight: 858.395
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: cis-bromobis{((1,3-dioxane-2-yl)methyl)diphenylphosphane-P;O',P'}palladium(II) perchlorate(CAS DataBase Reference)
NIST Chemistry Reference: cis-bromobis{((1,3-dioxane-2-yl)methyl)diphenylphosphane-P;O',P'}palladium(II) perchlorate(150266-91-4)
EPA Substance Registry System: cis-bromobis{((1,3-dioxane-2-yl)methyl)diphenylphosphane-P;O',P'}palladium(II) perchlorate(150266-91-4)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 150266-91-4(Hazardous Substances Data)

Suppliers
Usage
Upstream product
Downstream Products
Article

150266-91-4 Suppliers

Recommended suppliers

150266-91-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 150266-91-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,0,2,6 and 6 respectively; the second part has 2 digits, 9 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 150266-91:
(8*1)+(7*5)+(6*0)+(5*2)+(4*6)+(3*6)+(2*9)+(1*1)=114
114 % 10 = 4
So 150266-91-4 is a valid CAS Registry Number.

150266-91-4Upstream product

150266-91-4Downstream Products

150266-91-4Relevant academic research and scientific papers

Fluxional Behavior of Cationic cis-Bis(ether-phosphane)palladium(II) Complexes. - 31P-DNMR Spectroscopic Investigations, Line-Shape Analysis, and Determination of Rearrangement Barriers

Lindner, Ekkehard,Dettinger, Johannes,Mayer, Hermann August,Kuehbauch, Hartwig,Fawzi, Riad,Steimann, Manfred

, p. 1317 - 1324 (2007/10/02)

Reaction of X2Pd(PO)2 (X = Cl: 1a-g, k-n, p; X = Br: l'; X = I: k'', l'', o'') with stoichiometric amounts of AgClO4 results in the formation of the monochelate complexes cis-O)(PO)> (2a-g, k-n, p, l', l'') (PO: η1-P-coordinated; PO: η2-O,P-chelated).In the case of compounds 1o, 1k'', and 1o'', which are provided with less basic ether-phosphanes, the halide-bridged dimers O)2>22 (3o, k'', o'') are obtained.Temperature-dependent 31P-NMR spectra of the fluxional complexes 2a-g, k-n, p, l', l'' lead to ΔG(excit.)values.By using modified versions of DNMR5, computer-generated spectra of 2a, b, f, k, l, p, l', l'' were obtained and fitted to the experimental spectra.Graphic application of the Eyring equation to the kinetic data afforded the thermodynaic parameters ΔH(excit.), ΔS(excit.), and ΔG(excit.).The ΔS(excit.) values are in agreement with an associative exchange mechanism for 2a, b, f, l, p, l', l'' and with a dissociative exchange mechanism for 2k. 2k and 3o crystallize in the monoclinic and triclinic space group P21/c and P with Z = 4 and Z = 2, respectively.Key Words: Palladium complexes / Ether-phosphanes / NMR, 31P, dynamic, line-shape analysis / Fluxional behavior

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 150266-91-4