150268-72-7Relevant academic research and scientific papers
ω-Mono N-Alkylation of Linear Tetraamines through the Reaction of Aldehydes and Ketones on their Tricarbonyl Chromium, Molybdenum or Tungsten Complexes
Yaouanc, Jean-Jacques,Bris, Nathalie Le,Clement, Jean-Claude,Handel, Henri,Abbayes, Herve des
, p. 696 - 698 (2007/10/02)
The reductive amination of carbonyl compounds by the non-coordinated amino function of the fac-LM(CO)3 tridentate complexes of 1,4,7,10-tetraazadecane, 1,5,8,12-tetraazadodecane and 1,5,9,13-tetraazatridecane has been selectively achieved giving rise to ω
Mono N-Functionalization of Cyclic and Linear Tetraamines via Their Tridentate Tricarbonylchromium Complexes
Yaouanc, Jean-Jacques,Bris, Nathalie Le,Gall, Guenaelle Le,Clement, Jean-Claude,Handel, Henri,Abbayes, Herve des
, p. 206 - 207 (2007/10/02)
The fac-LCr(CO)3 tridentate complexes of 1,4,7,10-tetraazacyclododecane 1, 1,4,8,11-tetraazacyclotetradecane 2, 1,4,7,10-tetraazadecane 3 and 1,5,8,12-tetraazadodecane 4 have been shown selectively alkylated in high yield at the uncomplexed nitrogen atom, giving rise to mono N-functionalized tetraamines and bis-macrocyclic compounds.
