150282-06-7Relevant academic research and scientific papers
Environmentally benign strategy for arylation of nitronyl nitroxide using a non-Transition metal nucleophile
Nakamura, Fumiya,Naota, Takeshi,Suzuki, Shuichi
, p. 1350 - 1354 (2020)
We have developed a method for the arylation of nitronyl nitroxide without using its transition metal complex as a nucleophile. Various nitronyl nitroxide-substituted I -electronic compounds can be obtained from the parent nitronyl nitroxide and the corresponding aryl iodides using a combination of zero-valent palladium catalysts and a 2-dicyclohexylphosphino-2′,4′,6′-Triisopropylbiphenyl ligand in the presence of sodium tert-butoxide. The utility of the method has been demonstrated by the direct synthesis of open-shell compounds with giant I -electronic systems, such as 10P.
