150392-41-9

Basic information

• Product Name: dichloro(o-diphenylphosphino-N,N-dimethylaniline)(tris(p-tolyl)phosphine)ruthenium(II)
• Synonyms: dichloro(o-diphenylphosphino-N,N-dimethylaniline)(tris(p-tolyl)phosphine)ruthenium(II)
• CAS NO: 150392-41-9
• Molecular Weight: 781.707
• Mol File: 150392-41-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dichloro(o-diphenylphosphino-N,N-dimethylaniline)(tris(p-tolyl)phosphine)ruthenium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: dichloro(o-diphenylphosphino-N,N-dimethylaniline)(tris(p-tolyl)phosphine)ruthenium(II)(150392-41-9)
• EPA Substance Registry System: dichloro(o-diphenylphosphino-N,N-dimethylaniline)(tris(p-tolyl)phosphine)ruthenium(II)(150392-41-9)

Safety Data

• Hazardous Substances Data: 150392-41-9(Hazardous Substances Data)

Upstream product

• 1426385-01-4 C₄₁H₄₃Cl₂NOP₂Ru 

Downstream Products

• 150392-42-0 RuCl₂N₂(P(C₆H₄CH₃)3)((CH₃)2NC₆H₄P(C₆H₅)2) 
• 149863-14-9 RuCl₂H₂(P(C₆H₄CH₃)3)((CH₃)2NC₆H₄P(C₆H₅)2) 
• 149863-13-8 RuCl(H)(P(C₆H₄CH₃)3)((CH₃)2NC₆H₄P(C₆H₅)2) 

Relevant articles and documents

Reversible binding of water, methanol, and ethanol to a five-coordinate ruthenium(ii) complex

The known green, five-coordinate, square-pyramidal trans-RuCl 2(P-N)(PPh3) complex reversibly binds water, MeOH and EtOH in the vacant coordination site in the solid state and in CH2Cl 2 solution to give pink adducts (P-N = o-diphenylphosphino-N, N′-dimethylaniline). The adducts are well characterized, including X-ray analysis of the aqua complex, trans-RuCl2(P-N)(PPh 3)(H2O), which crystallizes in two different benzene-solvated forms. Comparison of the structural data with those determined previously for the binding of H2S, thiols, and H2, which form cis-RuX2(P-N)(PPh3)L products (X = Cl, Br; L = a S-ligand or H2) reveals the trans-influence trend P > H 2S ～ thiols > H2 > Cl ～ Br > H 2O. Thermodynamic data for the binding of water were estimated in solution by UV-Vis spectroscopy, and ΔHo data for the aqua and alcohol adducts in the solid state were obtained by differential scanning calorimetry. Inclusion of published data for the S-ligand adducts reveals the thermal stability trend of the solid complexes as MeSH > MeOH > H 2S > H2O > EtSH > EtOH.