150392-79-3

Basic information

• Product Name: trans-bis(4-picoline)(tetratolylporphyrinato)titanium(II)
• CAS NO: 150392-79-3
• Molecular Weight: 902.977
• Mol File: 150392-79-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-bis(4-picoline)(tetratolylporphyrinato)titanium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: trans-bis(4-picoline)(tetratolylporphyrinato)titanium(II)(150392-79-3)
• EPA Substance Registry System: trans-bis(4-picoline)(tetratolylporphyrinato)titanium(II)(150392-79-3)

Safety Data

• Hazardous Substances Data: 150392-79-3(Hazardous Substances Data)

Upstream product

• 108-89-4 picoline 
• 199998-28-2 trans-(meso-tetra-p-tolylporphyrinato)Ti(THF)2 
• 148509-02-8 (meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(η2-3-hexyne) 
• 129679-91-0 (meso-tetra-p-tolylporphyrinato)titanium(IV) dichloride 

Relevant articles and documents

Facile Syntheses of Titanium(II), Tin(II), and Vanadium(II) Porphyrin Complexes through Homogeneous Reduction. Reactivity of trans-(TTP)TiL2 (L = THF, t-BuNC)

Facile syntheses of the meso-tetra-p-tolylporphyrin (TTP) complexes trans-(TTP)Ti(THF)2 (1), (TTP)Sn (2), and trans-(TTP)V(THF)2 (3) are achieved through homogeneous reduction of high-valent precursors using NaBEt3H. The composition of the new compound trans-(TTP)Ti(THF)2 was determined by spectroscopic and chemical characterization. Ligand displacement reactions of trans-(TTP)Ti(THF)2 with t-BuNC produced a new Ti(II) complex, trans-(TTP)Ti(t-BuNC)2. The ligand-binding preference of (TTP)TiIILn (n = 1, 2) is picoline ～pyridine > t-BuNC > PhC≡CPh > EtC≡CEt > THF.