1504-73-0

Basic information

• Product Name: 3-(1-naphthyl)acrolein
• Synonyms: 3-(1-naphthyl)acrolein
• CAS NO: 1504-73-0
• Molecular Weight: 182.222
• Mol File: 1504-73-0.mol

Chemical Properties

• CAS DataBase Reference: 3-(1-naphthyl)acrolein(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(1-naphthyl)acrolein(1504-73-0)
• EPA Substance Registry System: 3-(1-naphthyl)acrolein(1504-73-0)

Safety Data

• Hazardous Substances Data: 1504-73-0(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 4780-79-4 1-naphthalene methanol 
• 3054-95-3 acrylaldehyde diethyl acetal 
• 90-11-9 1-Bromonaphthalene 

Downstream Products

• 1062144-19-7 C₂₃H₂₁NO₂ 
• 1170328-09-2 C₂₁H₂₂O₃ 
• 1277097-89-8 (1R,2S,3R,4R)-diisopropyl 1-hydroxy-3-(naphthalen-1-yl)-4-phenylcyclopentane-1,2-dicarboxylate 
• 1277097-92-3 C₂₃H₂₄O₃ 
• 1277097-93-4 (2R,3R,4R)-2-(hydroxymethyl)-3-(naphthalen-1-yl)-4-phenylcyclopentanone 

Relevant articles and documents

Supported palladium nanoparticles as switchable catalyst for aldehyde conjugate/s and acetate ester syntheses from alcohols

Polymer-supported Pd(0) (Pd@PS) nanoparticles (NPs) were explored as a switchable catalyst for oxidative aldehyde conjugate/s (AC/s) and acetate esters (AEs) syntheses from alcohols. Using the same substrates, the catalyst in the presence of oxygen and K2CO3 participated in AC/s synthesis, and in the presence of traces of air and NaOtBu, unusual AEs products were obtained.

Influence of the catalytic conditions on the selectivity of the Pd-catalyzed Heck arylation of acrolein derivatives

The Heck arylation of acrolein with a variety of condensed aryl and heteroaryl halides is described. Depending on the substrate, up to 87% isolated yield to the expected aldehydes was achieved. When the reaction was run on diethylacetal acrolein, the choice of catalytic system dramatically affected the selectivity of the reaction: the catalyst system based on Herrmann's palladacycle complex gave mainly saturated esters 2, whereas Cacchi's conditions led to the formation of α,β-unsaturated aldehydes 1.