150408-64-3Relevant academic research and scientific papers
Organometallic chemistry of diphosphazanes VIII. Synthesis, spectroscopic studies and crystal structure of fac-iPr)P(Ph)(DMP)>>, and its reactions with tertiary phosphines
Babu, R. P. Kamalesh,Krishnamurthy, S. S.,Nethaji, M.
, p. 157 - 163 (1993)
The reaction of fac- with the unsymmetrical diphosphazane Ph2PN(i-Pr)P(Ph)(DMP) (L) gives the complex fac- (2) in almost quantitative yield.The structure of the complex has been determined by an X-ray diffraction study.The compound reacts with PR3 (where R = Ph, OPh) to give fac- (3a, 4a), which undergoes an intramolecular isomerization to afford mer- (3b,4b).Synthesis of cis- (1) and fac- (2a) and their spectroscopic data are also reported.
