150429-78-0Relevant academic research and scientific papers
Heterodinuclear titanium-cobalt complexes: Syntheses and properties. X-ray structure of [(tC4H9O)3TiCo(CO)4] (Ti-Co)
Selent, Detlef,Beckhaus, Rüdiger,Pickardt, Joachim
, p. 2857 - 2860 (2008/10/08)
An X-ray structural investigation establishes an unbridged Ti-Co bond in [(tC4H9O)3Ti-Co(CO)4] (1a) and shows it to crystallize in the orthorhombic space group Pbn21, with a = 1192.5(7) pm, b = 1375.8(9) pm, c = 1405.0-(10) pm, and Z = 4. The variation of the alkoxide ligand leads to the more thermally unstable derivatives [(RO)3-TiCo(CO)4] (R = i-C3H7, CH(CF3)2, Ph), whereas trans-[(tC4H9O)3TiCo(CO) 3(PPh3)] is formed in a selective axial carbon monoxide ligand substitution reaction between 1a and triphenylphosphine.
