150483-61-7

Basic information

• Product Name: Benzoic acid, 2-(methylenehydrazino)-, ethyl ester (9CI)
• Synonyms: Benzoic acid, 2-(methylenehydrazino)-, ethyl ester (9CI)
• CAS NO: 150483-61-7
• Molecular Formula: C10H12N2O2
• Molecular Weight: 192.21448
• Product Categories: AMINOACID
• Mol File: 150483-61-7.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 299.9±42.0 °C(Predicted)
• Appearance: /
• Density: 1.08±0.1 g/cm3(Predicted)
• PKA: 12.18±0.10(Predicted)
• CAS DataBase Reference: Benzoic acid, 2-(methylenehydrazino)-, ethyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-(methylenehydrazino)-, ethyl ester (9CI)(150483-61-7)
• EPA Substance Registry System: Benzoic acid, 2-(methylenehydrazino)-, ethyl ester (9CI)(150483-61-7)

Safety Data

• Hazardous Substances Data: 150483-61-7(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 144366-37-0 N-methyl-2-nitrosobenzamide 

Relevant articles and documents

Electrosynthesis and in situ chemical rearrangement of o-nitrosobenzamides

Primary and secondary o-nitrosobenzamides can be prepared in a "redox" cell but are unstable in the solvent used for electrolysis (acetate buffer-alcohol).At room temperature N-aryl-2-nitrosobenzamides give 2-carboxyazobenzenes.N-alkyl-2-nitrosobenzamides decompose thermally into 2-methoxy or 2-ethoxycarbonylphenylhydrazones according to the alcohol used.Similarly, methyl benzoate (or ethyl benzoate) is obtained from 2-nitrosobenzamide.A possible mechanism involves an unstable heterocycle formed by the coupling of the two nitrogen atoms (nitroso and amide) followed by cleavage of the carbonyl-nitrogen bond resulting from nucleophilic attack of the solvent (water or alcohol). Key Words: flow cell electrosynthesis / 2-nitrosobenzamides / 2-carboxyazobenzenes / 2-alkoxycarbonylphenylhydrazones / indazol-3-one