150493-29-1

Basic information

• Product Name: (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER
• Synonyms: (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER;TERT-BUTYL (1,2-METHANOFULLERENE C60)-61-CARBOXYLATE
• CAS NO: 150493-29-1
• Molecular Formula: C₆₆H₁₀O₂
• Molecular Weight: 834.7844
• Mol File: 150493-29-1.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER(150493-29-1)
• EPA Substance Registry System: (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER(150493-29-1)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• F: 8
• Hazardous Substances Data: 150493-29-1(Hazardous Substances Data)

Usage

General Description

(1,2-Methanofullerene C60)-61-carboxylic acid tert-butyl ester is a chemical compound that is derived from fullerenes, which are carbon molecules arranged in a unique spherical shape. This particular compound contains a carboxylic acid group and a tert-butyl ester group attached to a C60 molecule. It is commonly used in organic synthesis and materials science due to its unique structure and properties. Additionally, it has been investigated for potential applications in drug delivery, photovoltaic devices, and as a building block for supramolecular assemblies. Its chemical structure and properties make it a versatile and valuable compound for various applications in the field of chemistry and materials science.

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Downstream Products

• 155116-19-1 1,2-dihydro-1,2-methanofullerene[60]-61-carboxylic acid 

Relevant articles and documents

Methanofullerenes, C60(CH2)n (n = 1, 2, 3), as building blocks for high-performance acceptors used in Organic Solar Cells

Selective preparation of C60(CH2)n (n = 1, 2, 3) was realized via a Bingel-decarboxylation route. A 54p- electron derivative of C60(CH2)2, OQBMF, demonstrates an outstanding power conversion efficiency (PCE) of 6.43% (Voc = 0.95 V, Jsc = 9.67 mA cm-2, FF = 70%) in fullerene:P3HT solar cells since the small CH2 addends lift up fullerene LUMO and increase Voc significantly without decreasing mobility significantly.

Toward controlled spacing in one-dimensional molecular chains: Alkyl-chain-functionalized fullerenes in carbon nanotubes

A range of fullerenes (C60) functionalized with long alkyl chains have been synthesized and inserted into single-walled carbon nanotubes. The impact of the alkyl chain length and of the type of linker between the addend and the fullerene cage on the geometry of molecular arrays in nanotube has been studied by high-resolution transmission electron microscopy. In the presence of functional groups the mean interfullerene separations are significantly increased by 2-8 nm depending on the length of the alkyl chain, but the periodicity of the fullerene arrays is disrupted due to the conformational flexibility of the alkyl groups.

CuBr/PMDETA-mediated reactions of [60]fullerene with active halides: Preparation of methano[60]fullerene derivatives

An efficient protocol for the synthesis of methano[60]fullerene derivatives linked with a single electron-withdrawing group has been developed through one-step reaction of [60]fullerene with active halides mediated by CuBr/pentamethyldiethylenetriamine. M

Cycloaddition of diazoacetates to C60 fullerene catalysed by Pd complexes

An efficient catalytic method of the cycloaddition to C60 fullerene of the diazoacetates, containing substituents of diverse structures in ester groups, in the presence of a Pd-based three-component catalyst was developed. An influence of nature and the structure of substituent in the ester group on the activity of diazoacetates in the reaction with C60 was studied. Yields of respective cycloadducts were determined.