150512-62-2Relevant academic research and scientific papers
Radical Transformation of Aliphatic C-H Bonds to Oxime Ethers via Hydrogen Atom Transfer
Wang, Xinmou,Yu, Mo,Song, Hongjian,Liu, Yuxiu,Wang, Qingmin
supporting information, p. 8353 - 8358 (2021/10/25)
Herein, we describe a strategy for conversion of aliphatic C-H bonds to oxime ethers via hydrogen atom transfer. In this strategy, the decatungstate anion and sulfate radical play complementary roles in the abstraction of hydrogen atoms from primary, secondary, and tertiary C-H bonds of alkanes. The easy accessibility of alkanes and the broad substrate scope, mild conditions, and excellent regioselectivity of these reactions make this strategy applicable for the transformation of raw materials to high-value chemicals.
Manganese complexes of nitrogen-containing macrocyclic ligands effective as catalysts for dismutating superoxide
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, (2008/06/13)
The present invention is directed to low molecular weight mimics of superoxide dismutase (SOD) represented by the formula: STR1 wherein R, R', R1, R'1, R2, R'2, R3, R'3, R4, R'4, R5, R'5, R6, R'6, R7, R'7, R8, R'8, R9, and R'9 and X, Y, Z and n are as defined herein, useful as therapeutic agents for inflammatory disease states and disorders, ischemic/reperfusion injury, stroke, atherosclerosis, hypertension and all other conditions of oxidant-induced tissue damage or injury.
Methods of preparing manganese complexes of nitrogen-containing macrocyclic ligands
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, (2008/06/13)
The present invention is directed to low molecular weight mimics of superoxide dismutase (SOD) represented by the formula: STR1 wherein R, R', R1, R'1, R2, R'2, R3, R'3, R4, R'4, R5, R'5, R6, R'6, R7, R'7, R8, R'8, R9, and R'9 and X, Y, Z and n are as defined herein, useful as therapeutic agents for inflammatory disease states and disorders, ischemic/reperfusion injury, stroke, atherosclerosis, hypertension and all other conditions of oxidant-induced tissue damage or injury.
Convenient method for one-pot preparation of 1,2-diamines from nitroolefins
Imagawa, Kiyomi,Hata, Eiichiro,Yamada, Tohru,Mukaiyama, Teruaki
, p. 291 - 292 (2007/10/03)
Convenient method for preparation of 1,2-diamine from the corresponding nitroolefin was established by successive reactions of Michael addition of O-ethylhydroxylamine to nitroolefin and reduction with hydrogen. The present preparative method was applicable to various nitroolefins by one-pot procedure.
