150582-54-0Relevant articles and documents
Some unexpected reactions of 2,2-bis-(trifluoromethyl)-1,3-oxazolidin-5-ones
Radics, Gabor,Schedel, Hartmut,Heistracher, Elisabeth,Sieler, Joachim,Hennig, Lothar,Burger, Klaus
, p. 213 - 225 (2007/10/03)
2,2-Bis(trifluoromethyl)-1,3-oxazolidin-5-ones and hexafluoroacetone react in dimethyl sulfoxide to give trifluoromethyl substituted 1,3-oxazolidine-4-carboxylate, 3-amino-5,5-bis(trifluoromethyl)-2(5H)-furanone and 4-amino-2,2-bis(trifluoromethyl)-1,3-dioxolanes depending on the substituent pattern of the amino acid. All compounds are formed via a common intermediate, namely N-hexafluoroisopropylidene α-amino acids.