150592-41-9

Upstream product

• 35303-86-7 (2R,3S,4S,5R,6S)-3,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-ol 
• 75-78-5 dimethylsilicon dichloride 

Downstream Products

• 150592-42-0 phenylthio 2-O-dimethyl-(1-O-methyl-2,4,6-tri-O-benzyl-α-D-glucopyranos-3-oxyl)-silyl-3,4,6-tri-O-acetyl-α-D-glucopyranoside 

Relevant academic research and scientific papers

Efficient stereocontrolled glycosidation of secondary sugar hydroxyls by silicon tethered intramolecular glycosidation

Dissaccharides containing 1,2-cis glycoside linkages were synthesized by an efficient stereocontrolled two step process involving a silicon tethering step, to a dimethylsilyl acetal followed by intramolecular glycosidation with N-iodosuccinimide in nitrom

Application of Intramolecular Glycosidation to the Stereocontrolled Synthesis of Disaccharides containing α-Gluco and α-Galacto Linkages

Disaccharides containing α-glucose and α-galactose linkages are stereospecifically synthesized from primary and secondary sugar hydroxy groups and a 2-hydroxythioglycoside via intramolecular glycosidation of a dimethylsilyl tethered intermediate.