150615-32-0Relevant academic research and scientific papers
A Novel and Stereodefined Synthesis of (E)-β-Ethoxycarbonylvinylsilanes: Regio- and Stereo-controlled Hydroethoxycarbonylation of Silylacetylenes by Palladium(II) Catalysis
Takeuchi, Ryo,Sugiura, Masaharu
, p. 1031 - 1038 (2007/10/02)
-SnCl2*2H2O catalysed hydroethoxycarbonylation of silylacetylenes 1 provided a novel and convenient synthesis of (E)-β-ethoxycarbonylvinylsilanes 2.The reactions, carried out under mild conditions (90 deg C, 20 kg cm-2) gave the pr
