150618-98-7

Basic information

• Product Name: 2-(4-chlorophenyl)-5-((trifluoromethyl)thio)-1H-pyrrole
• Synonyms: 2-(4-chlorophenyl)-5-((trifluoromethyl)thio)-1H-pyrrole
• CAS NO: 150618-98-7
• Molecular Weight: 277.697
• Mol File: 150618-98-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(4-chlorophenyl)-5-((trifluoromethyl)thio)-1H-pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-chlorophenyl)-5-((trifluoromethyl)thio)-1H-pyrrole(150618-98-7)
• EPA Substance Registry System: 2-(4-chlorophenyl)-5-((trifluoromethyl)thio)-1H-pyrrole(150618-98-7)

Safety Data

• Hazardous Substances Data: 150618-98-7(Hazardous Substances Data)

Upstream product

• 19867-89-1 2-(4-chlorophenyl)-1H-pyrrole 
• 421-83-0 trifluoromethane sulfonyl chloride 
• 1443036-49-4 1-phenyl-2-(phenyl-λ³-iodaneylidene)-2-((trifluoromethyl)sulfonyl)ethan-1-one 

Downstream Products

• 150618-99-8 3-bromo-2-(p-chlorophenyl)-5-[(trifluoromethyl)thio]pyrrole 
• 150619-05-9 2-(p-chlorophenyl)-3-nitro-5-[(trifluoromethyl)thio]pyrrole 
• 150619-06-0 5-(p-chlorophenyl)-3-nitro-2-[(trifluoromethyl)thio]pyrrole 

Relevant articles and documents

Copper-catalyzed regioselective trifluoromethylthiolation of pyrroles by trifluoromethanesulfonyl hypervalent iodonium ylide

The copper-catalyzed trifluoromethylthiolation of pyrroles with a trifluoromethanesulfonyl hypervalent iodonium ylide under mild conditions has been achieved. A broad set of pyrroles could be transformed to the corresponding products in moderate to excellent yields. The reaction mechanism is hypothesized.