150640-22-5

Upstream product

• 75-52-5 nitromethane 
• 103-19-5 di(p-tolyl) disulfide 
• 933-00-6 p-methylbenzenesulfenyl chloride 
• 106-45-6 para-thiocresol 

Downstream Products

• 150640-12-3 (Z)-(4S)-2,2-dimethoxy-4-<2'-<4''-(methylphenyl)thio>-2'-nitroethenyl>-1,3-dioxolane 
• 51351-89-4 nitromethyl p-tolyl sulfone 
• 157661-82-0 Z-(4S,5S)-2,2-dimethyl-5-<(tert-butyldimethylsilyloxy)methyl>-4-<2'-<(4''-methylphenyl)thio>-2'-nitroethenyl>-1,3-dioxolane 
• 499783-30-1 ((S)-1-Benzyl-2-hydroxy-3-nitro-3-p-tolylsulfanyl-propyl)-carbamic acid tert-butyl ester 
• 499783-28-7 ((S)-2-Hydroxy-1-methyl-3-nitro-3-p-tolylsulfanyl-propyl)-carbamic acid tert-butyl ester 
• 499783-32-3 ((S)-2-Hydroxy-3-nitro-1-phenyl-3-p-tolylsulfanyl-propyl)-carbamic acid tert-butyl ester 
• 160349-77-9 (1Z,3S)-3-tert-butyldimethylsilyloxy-1-(4'-methylphenylthio)-1-nitrobut-1-ene 
• 228716-83-4 3-(tert-butyl-dimethyl-silanyloxy)-1-nitro-1-p-tolylsulfanyl-butan-2-ol 
• 228716-84-5 (1Z,3R)-3-tert-butyldimethylsilyloxy-4-methyl-1-(4'-methylphenylthio)-1-nitropent-1-ene 
• 499783-34-5 (2-hydroxy-1-methyl-3-nitro-3-p-tolylsulfanyl-propyl)-carbamic acid benzyl ester 
• 1054620-96-0 (S)-Amino-[(4S,5S)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-thioacetic acid S-p-tolyl ester 
• 80-48-8 methyl p-toluene sulfonate 

Relevant academic research and scientific papers

Cs2CO3-promoted carbon–sulfur bond construction via cross dehydrogenative coupling of thiophenols with acetonitrile

A novel protocol for the construction of carbon–sulfur bonds has been achieved via halogen-free Cs2CO3-promoted cross dehydrogenative coupling (CDC) of thiophenols with acetonitrile. This transformation provides a straightforward route to the synthesis of sulfenylated acetonitriles in up to 80% yield.

Sulfenylation of nitroalkanes and hydroxyaryls

The sulfenylation of nitroalkanes and hydroxyaryls in DMSO using aryl disulfides as sulfenylating reagents was studied. The corresponding arylthionitroalkanes and arylthiohydroxyaryls were obtained in moderate to good yields in very mild conditions, thus improving the reported procedures for the synthesis of these compounds.

Sulfonyl Esters. V. A Preparation of Dichloromethyl Sulfones

α-Sulfonyl methyl esters have been chlorinated in the presence of base.Chlorination proceeds with accompanying demethoxycarbonylation to furnish dichloromethyl sulfones in good yields.