150701-10-3Relevant academic research and scientific papers
meta-Selective C?H Borylation of Benzylamine-, Phenethylamine-, and Phenylpropylamine-Derived Amides Enabled by a Single Anionic Ligand
Davis, Holly J.,Genov, Georgi R.,Phipps, Robert J.
supporting information, p. 13351 - 13355 (2017/10/07)
Selective functionalization at the meta position of arenes remains a significant challenge. In this work, we demonstrate that a single anionic bipyridine ligand bearing a remote sulfonate group enables selective iridium-catalyzed borylation of a range of common amine-containing aromatic molecules at the arene meta position. We propose that this selectivity is the result of a key hydrogen bonding interaction between the substrate and catalyst. The scope of this meta-selective borylation is demonstrated on amides derived from benzylamines, phenethylamines and phenylpropylamines; amine-containing building blocks of great utility in many applications.
Synthesis and photophysical properties of new 2,2′-bipyridine-bridged bis[ruthenium(II)tris-2,2′-bipyridine] complexes
Koenig, Burkhard,Zicg, Harald,Nimtz, Manfred,Cola, Luisa D.C.,Balzani, Vincenzo
, p. 529 - 533 (2007/10/03)
GBF (Gesellschaft fuer Biotechnologische Forschung mbH) b, Mascheroder Weg l, D-38124 Braunschweig, Germany Dipartimento di Chimica "G. Ciamician", Universite di Bologna c, via Selmi 2, 1-40126 Bologna, Italy We have synthesized a new type of tris-2,2′-bi
An Electro-photoswitch: Redox Switching of the Luminescence of a Bipyridine Metal Complex
Goulle, Veronique,Harriman, Anthony,Lehn, Jean-Marie
, p. 1034 - 1036 (2007/10/02)
The redox couple 1/2 represents an electro-photoswitching device displaying electrochemically reversible interconversion between a non-luminescent state 1 and a luminescent state 2.
