150701-10-3

Basic information

• Product Name: 2,2'-Bipyridine, 4-[(diphenylphosphinyl)methyl]-4'-methyl-
• CAS NO: 150701-10-3
• Molecular Formula: C24H21N2OP
• Molecular Weight: 384.417
• Mol File: 150701-10-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2'-Bipyridine, 4-[(diphenylphosphinyl)methyl]-4'-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-Bipyridine, 4-[(diphenylphosphinyl)methyl]-4'-methyl-(150701-10-3)
• EPA Substance Registry System: 2,2'-Bipyridine, 4-[(diphenylphosphinyl)methyl]-4'-methyl-(150701-10-3)

Safety Data

• Hazardous Substances Data: 150701-10-3(Hazardous Substances Data)

Upstream product

• 1134-35-6 4,4'-dimethyl-2,2'-bipyridines 
• 1499-21-4 Diphenylphosphinic chloride 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 150701-11-4 4-[(E)-2-(2,5-Dimethoxy-phenyl)-vinyl]-4'-methyl-[2,2']bipyridinyl 

Relevant articles and documents

meta-Selective C?H Borylation of Benzylamine-, Phenethylamine-, and Phenylpropylamine-Derived Amides Enabled by a Single Anionic Ligand

Selective functionalization at the meta position of arenes remains a significant challenge. In this work, we demonstrate that a single anionic bipyridine ligand bearing a remote sulfonate group enables selective iridium-catalyzed borylation of a range of common amine-containing aromatic molecules at the arene meta position. We propose that this selectivity is the result of a key hydrogen bonding interaction between the substrate and catalyst. The scope of this meta-selective borylation is demonstrated on amides derived from benzylamines, phenethylamines and phenylpropylamines; amine-containing building blocks of great utility in many applications.

An Electro-photoswitch: Redox Switching of the Luminescence of a Bipyridine Metal Complex

The redox couple 1/2 represents an electro-photoswitching device displaying electrochemically reversible interconversion between a non-luminescent state 1 and a luminescent state 2.