15074-38-1Relevant academic research and scientific papers
Palladium complex catalyzed Si-Si bond metathesis dimerization of 3,4-benzo-1,2-dimethyl-1,2-diethyl-1,2-disilacyclobut-3-ene and isomerization of the resulting and relevant dimers
Uchimaru, Yuko,Tanaka, Masato
, p. 335 - 341 (1996)
Palladium-phosphine complex catalyzed Si-Si bond metathesis dimerization of 3,4-benzo-1,2-dimethyl-1,2-diethyl-1,2-disilacyclobut-3-ene (1b) took place at 80°C to give 3,4,7,8-dibenzo-1,2,5,6-tetramethyl-1,2,5,6-tetraethyl-1,2,5,6-tetrasilacycloocta-3,7-d
Nickel(0) catalyzed oxidation of organosilanes to disiloxanes by air as an oxidant
Lv, Haiping,Laishram, Ronibala Devi,Li, Jiayan,Shi, Guangrui,Sun, Weiqing,Xu, Jianbin,Yang, Yong,Luo, Yang,Fan, Baomin
supporting information, p. 971 - 974 (2019/03/07)
We report here an efficient non-aqueous route to symmetrical disiloxanes from their corresponding organosilanes using Ni(COD)2 with 3,4,7,8-tetramethyl-1,10-phenanthroline in air. Our methodology is very simple and high yielding. The reaction mechanism is also proposed.
Synthesis of a new hypervalent iodine compound, [2-(hydroxydimethylsilyl)phenyl](phenyl)iodonium triflate as a convenient approach to benzyne
Kitamura,Meng,Fujiwara
, p. 6611 - 6614 (2007/10/03)
A new benzyne precursor, [2-(hydroxydimethylsilyl)phenyl](phenyl)iodonium triflate, is prepared from 1,2-dibromobenzene in good yield. This procedure avoids the use of carcinogenic HMPA and the severe reaction conditions. The reaction of the benzyne precursor with Bu4NF in the presence of a trapping agent under very mild conditions efficiently generates benzyne and gives the benzyne adduct in high yield. (C) 2000 Elsevier Science Ltd.
THE FIRST SUCCESSFUL RING OPENING POLYMERIZATION AT THE Si-Si BOND: A NOVEL o-(DISILANYLENE)PHENYLENE POLYMER
Shiina, Kyo
, p. C57 - C59 (2007/10/02)
A new type of polymer, poly was prepared via ring opening polymerization, at the Si-Si bond, of 1,1,2,2-tetramethyl-1,2-disilabenzocyclobutene.
