150783-30-5

Basic information

• Product Name: 3-methyl-2'-nitrobutananilide
• Synonyms: 3-methyl-2'-nitrobutananilide
• CAS NO: 150783-30-5
• Molecular Weight: 222.244
• Mol File: 150783-30-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-methyl-2'-nitrobutananilide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-2'-nitrobutananilide(150783-30-5)
• EPA Substance Registry System: 3-methyl-2'-nitrobutananilide(150783-30-5)

Safety Data

• Hazardous Substances Data: 150783-30-5(Hazardous Substances Data)

Upstream product

• 503-74-2 3-methylbutyric acid 
• 55557-13-6 3-methylbutyric acid trimethylsilyl ester 
• 88-74-4 2-nitro-aniline 

Relevant articles and documents

An Effective Method for Acylation of Weakly Nucleophilic Anilines with Silyl Carboxylates via Mixed Anhydrides

In the presence of a catalytic amount of active titanium(IV) salt generated in situ from 1 mol of TiCl4 and 2 mol of AgOTf, weakly nucleophilic anilines react under mild conditions with nearly equimolar amounts of silyl carboxylates to afford the corresponding anilides in excellent yields using 4-(trifluoromethyl)benzoic anhydride.The mixed anhydride formed in situ from trimethylsilyl acetate and 4-(trifluoromethyl)benzoic anhydride, a key intermediate of this reaction, was detected by 1H NMR experiment.Further, it was shown that the reaction of the mixed anhydrides and 2-nitroaniline was faster than that of the corresponding homo anhydrides and 2-nitroaniline.