15080-14-5Relevant academic research and scientific papers
Charge transfer complex formation between p-chloranil and 1,n-di(9-anthryl)alkanes
Arslan, Mustafa,Masnovi, John
, p. 711 - 716 (2007/10/03)
Dimer model compounds of polyvinylanthracenes (1,n-di(9-anthryl)alkanes, when n = 1-5) were synthesized to model the effects of distance and orientation between anthracene groups in polymeric systems. Charge transfer (CT) complexes of anthracene, 9-methylanthracene and 1,n-di(9-anthryl)alkanes with p-chloranil (p-CHL) have been investigated spectrophotometrically in dichloromethane. The colored products are measured spectrophotometrically at different wavelength depending on the electronic transition between donors and acceptor. The formation constants of the CT complexes were determined by the Benesi-Hildebrand equation. The thermodynamic parameters were calculated by Van't Hoff equation. Stochiometries of the complexes formed between donors and acceptor were defined by the Job's method of the continuous variation and found in 1:1 complexation with donor and acceptor at the maximum absorption bands.
Reaction of 9-α-Chloronaphthylmethylanthracene and Its Homologues with Nucleophiles under Solvolytic Conditions. Effect of the Increase of Bulk at C-α on the Reaction Site
Takagi, Masato,Nojima, Masatomo,Kusabayashi, Shigekazu
, p. 2637 - 2641 (2007/10/02)
The reaction of 9-α-chloronaphthylmethylanthracene and its homologues with (a) sodium ethoxide in ethanol, (b) ethanol in the presence of triethylamine, (c) sodium borohydride in aqueous diglyme, and (d) sodium azide in aqueous NN-dimethylformamide has gi
