150841-75-1Relevant articles and documents
Enantioselective silicon-mediated synthesis of glyceraldehyde derivatives from propargyl alcohol
Raubo,Wicha
, p. 1273 - 1288 (2007/10/02)
Asymmetric epoxidation of 3-(trimethylsilyl)allyl alcohol affords epoxysilane 5 of high optical purity. Silica gel-catalyzed addition of benzenethiol to epoxide 5 affords sulfide 8 which was transformed into 2S)-2,3-0-isopropylideneglyceraldehyde 2 and the glyceraldehyde derivative 3.