15088-90-1

Basic information

• Product Name: N-phenyl-4-(propan-2-yl)benzamide
• Synonyms: 4-Isopropyl-N-phenylbenzamide; benzamide, 4-(1-methylethyl)-N-phenyl-
• CAS NO: 15088-90-1
• Molecular Formula: C₁₆H₁₇NO
• Molecular Weight: 239.3123
• Mol File: 15088-90-1.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 301°C at 760 mmHg
• Flash Point: 181.1°C
• Density: 1.095g/cm³
• Vapor Pressure: 0.00108mmHg at 25°C
• Refractive Index: 1.603
• CAS DataBase Reference: N-phenyl-4-(propan-2-yl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenyl-4-(propan-2-yl)benzamide(15088-90-1)
• EPA Substance Registry System: N-phenyl-4-(propan-2-yl)benzamide(15088-90-1)

Safety Data

• Hazardous Substances Data: 15088-90-1(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 536-60-7 cuminol 
• 201230-82-2 carbon monoxide 
• 16152-51-5 (4-isopropylphenyl)boronic acid 
• 21900-62-9 p-isopropylbenzoyl chloride 
• 18864-76-1 4-isopropylbenzophenone 
• 10026-13-8 phosphorus pentachloride 

Relevant articles and documents

Method for synthesizing amide compound through photocatalysis in water phase

The invention discloses a method for synthesizing an amide compound through photocatalysis in a water phase. The method comprises the following steps: putting catalysis amounts of a free radical initiator, an amine derivative, a carboxylic acid derivative, a phase transfer catalyst, an inorganic base and water into a reaction container, carrying out a reaction in a photocatalysis reaction instrument at certain power under a room temperature condition, after a certain time, carrying out extraction by using a small amount of ethyl acetate, and carrying out recrystallization, so as to obtain theamide compound, wherein the free radical initiator is eosin, methyl orange, sodium persulfate, ammonium persulfate or potassium peroxodisulfate, the phase transfer catalyst is tetrabutylammonium bromide, and the power of the photocatalytic reaction instrument is 5W. By adopting the method disclosed by the invention, toxic thionyl chloride or phosphorus oxychloride is not needed for a chlorinationreaction, water is adopted as a solvent, a novel photocatalysis method is used, and the amide compound with a high yield can be prepared through a room-temperature reaction for 2-5 hours with an incandescent light bulb of 5W, and in addition, the method is simple in aftertreatment, and low in cost and is an ideal green synthesis method of amide compounds.

Aerobic oxidative transformation of primary alcohols and amines to amides promoted by a hydroxyapatite-supported gold catalyst in water

In the presence of an easily prepared hydroxyapatite-supported gold catalyst, namely Au/HAP, various kinds of structurally diverse primary alcohols including benzylic and aliphatic ones, and amines involving aromatic and secondary ones could be converted into the corresponding amides in water with up to 99% yield. Meanwhile, on the basis of experimental observations and literatures, a plausible reaction pathway was described to elucidate the reaction mechanism.