150895-40-2Relevant academic research and scientific papers
Total syntheses of ent-conduramine A and ent-7-deoxypancratistatin
Akguen, Huelya,Hudlicky, Tomas
, p. 3081 - 3084 (1999)
The first total synthesis of the title alkaloid has been accomplished in fourteen steps form 1-bromo-4-iodobenzene or 1-fluoro-4-iodobenzene via chemoenzymatic production of the antipedal cis-diene diols 4.
Stereodirecting Substituent Effects during Enzyme-catalysed Synthesis of cis-Dihydrodiol Metabolites of 1,4-Disubstituted Benzene Substrates
Boyd, Derek R.,Sharma, Narain D.,Hand, Mark V.,Groocock, Melanie R.,Kerley, Nuala A.,et al.
, p. 974 - 976 (2007/10/02)
The cis-dihydrodiol enantiomer preferentially formed, by dioxygenase-catalysed oxidation of 1,4-disubstituted benzene substrates in growing cultures of Pseudomonas putida UV4, is found to be largely controlled by the relative size of the substituents.
