150929-70-7Relevant academic research and scientific papers
Rotational Isomerism of Disubstituted Benzenes in the Alkylphenyldi(1-adamantyl)methanol Series
Lomas, John S.,Bru-Capdeville, Veronique
, p. 459 - 466 (2007/10/02)
Addition of di(1-adamantyl) ketone to the appropriate tolyllithium compounds gives all five positional and rotational isomers of tolyldi(1-adamantyl)methanol, as evidenced by 1H and 13C NMR spectroscopy.Synthesis of the ortho-substituted derivatives gives
(13)C NMR Spectroscopic Study of Para-Substituent Effects in Highly Crowded 1,1'-Diadamantylbenzyl Cations
Olah, George A.,Heagy, Michael D.,Prakash, G. K. Surya
, p. 4851 - 4854 (2007/10/02)
A series of para-substituted 1,1'-diadamantylbenzyl cations were studied under stable ion conditions at low temperatures in superacid solutions.These studies were informative in probing the effects of ring substituents and their ability to delocalize posi
