15093-49-9Relevant academic research and scientific papers
Nickel(II) complexes of di- and tri-substituted thiourea mono- and di-anions
Yuen, Ho Ying,Henderson, William,Oliver, Allen G.
body text, p. 1 - 5 (2011/05/04)
Reaction of nickel(II) acetate, 1,2-bis(diphenylphosphino)ethane (dppe), and a di- or tri-substituted thiourea R1NHC(S)R2R 3 (R3 = H or alkyl) with trimethylamine in hot methanol gave cationic nickel(II) complex
Insertion of arynes into thioureas: A new amidine synthesis
Biswas, Kallolmay,Greaney, Michael F.
supporting information; experimental part, p. 4946 - 4949 (2011/11/06)
Arynes, generated from trimethylsilyl phenyltriflate precursors, have been found to react with thioureas via a formal π-insertion into the C=S bond. The reaction contrasts with that of ureas, which proceeds via benzyne σ-insertion into the C-N bond, and r
