15096-05-6

Usage

Uses

Used in Pharmaceutical Industry:
(6Z)-6-[(4-methoxyphenyl)hydrazono]-4-methylcyclohexa-2,4-dien-1-one is used as a potential pharmaceutical compound for its unique structure and properties. (6Z)-6-[(4-methoxyphenyl)hydrazono]-4-methylcyclohexa-2,4-dien-1-one's hydrazone nature and cyclohexadienone ring may offer opportunities for the development of new drugs, targeting specific diseases or conditions.
Used in Agrochemical Industry:
In the agrochemical industry, (6Z)-6-[(4-methoxyphenyl)hydrazono]-4-methylcyclohexa-2,4-dien-1-one may be utilized as a starting material or intermediate for the synthesis of novel agrochemicals, such as pesticides or herbicides, due to its specific structural features.
Used in Materials Science:
(6Z)-6-[(4-methoxyphenyl)hydrazono]-4-methylcyclohexa-2,4-dien-1-one's unique structure and properties could also make it a candidate for applications in materials science. It may be investigated for its potential to contribute to the development of new materials with specific properties, such as improved strength, flexibility, or chemical resistance.

Upstream product

• 106-44-5 p-cresol 
• 17333-79-8 p-methoxybenzenediazonium 
• 119-33-5 4-methyl-2-nitrophenol 
• 459-64-3 4-methoxybenzenediazonium tetrafluoroborate 

Downstream Products

• 335001-38-2 Os(P(C₆H₅)3)2Br(CH₃OC₆H₃N₂C₆H₃(CH₃)O) 
• 602314-66-9 Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNC₆H₃OCH₃) 
• 226999-80-0 [Ru(CH₃COCHCOCH₃)(CH₃C₆H₃(O)N₂C₆H₄OCH₃)2] 
• 652131-96-9 [Ir(P(C₆H₅)3)2(CH₃OC₆H₄N₂C₆H₃(CH₃)O)(H)2] 
• 652131-97-0 [Ir(P(C₆H₅)3)2(CH₃OC₆H₃N₂C₆H₃(CH₃)O)(H)] 
• 652131-95-8 [Ir(P(C₆H₅)3)2(CH₃OC₆H₄N₂C₆H₃(CH₃)O)(H)Cl] 
• 1006709-34-7 [Ru(OC₆H₃(CH₃)N₂C₆H₃OC₂H₅)(CO)(As(C₆H₅)3)2] 
• 330685-06-8 [Rh(P(C₆H₅)3)2(CH₃OC₆H₃N₂OC₆H₃CH₃)Cl] 
• 874298-58-5 carbonyl(2-(4'-methoxyphenylazo)-4-methylphenolato^(2-)-C(2'),N⁽¹⁾,O)bis(triphenylphosphine)ruthenium 
• 874298-53-0 carbonylhydrido(2-(4'-methoxyphenylazo)-4-methylphenolato-N⁽¹⁾,O)bis(triphenylphosphine)ruthenium 
• 26054-09-1 4-acetoxy-3-(4-methoxy-phenylazo)-toluene 

Relevant academic research and scientific papers

A Chemoselective Rapid Azo-Coupling Reaction (CRACR) for Unclickable Bioconjugation

Chemoselective modification of complex biomolecules has become a cornerstone of chemical biology. Despite the exciting developments of the past two decades, the demand for new chemoselective reactions with unique abilities, and those compatible with existing chemistries for concurrent multisite-directed labeling, remains high. Here we show that 5-hydroxyindoles exhibit remarkably high reactivity toward aromatic diazonium ions and this reaction can be used to chemoselectively label proteins. We have previously genetically encoded the noncanonical amino acid 5-hydroxytryptophan in both E. coli and eukaryotes, enabling efficient site-specific incorporation of 5-hydroxyindole into virtually any protein. The 5-hydroxytryptophan residue was shown to allow rapid, chemoselective protein modification using the azo-coupling reaction, and the utility of this bioconjugation strategy was further illustrated by generating a functional antibody-fluorophore conjugate. Although the resulting azo-linkage is otherwise stable, we show that it can be efficiently cleaved upon treatment with dithionite. Our work establishes a unique chemoselective "unclickable" bioconjugation strategy to site-specifically modify proteins expressed in both bacteria and eukaryotes.

Aryliminodimagnesium Reagents. XVI. Formation of o-Hydroxyazoarenes by Condensation with o-Hydroxynitroarenes. Favorable Role of o-Hydroxyl Group in the Reaction

Hydroxy(HO)-azoxy and -azoarenes were formed by condensation of ArN(MgBr)2 with o-, m-, and p-HO-nitrobenzenes; nuclear substitution took place as a minor or a major pathway. o-HO-azobenzene was obtained in sufficiently high yield.Relative yields of the products varied according to the position of HO group and reaction conditions.The yield variation was explained by the effects of relative efficiency of single electron transfer, ?-complexation, and cooperation of reagent molecules.