1509945-39-4Relevant academic research and scientific papers
Cobalt-Catalysed C–C Bond Formation and [2+2+2] Annulation of 1,3-Dicarbonyls to Terminal Alkynes
Verma, Girijesh Kumar,Rawat, Manish,Rawat, Diwan S.
, p. 4101 - 4104 (2019)
A highly regioselective [Cp*Co(CO)I2]-catalyzed addition of 1,3-diketones to terminal alkynes at room temperature has been achieved using Cu(OTf)2 as a co-catalyst. The reaction of 1,3-diketones substituted at active methylene carbon
Synergistic Au/Ga catalysis in ambient nakamura reaction
Xi, Yumeng,Wang, Dawei,Ye, Xiaohan,Akhmedov, Novruz G.,Petersen, Jeffrey L.,Shi, Xiaodong
supporting information, p. 306 - 309 (2014/01/23)
The gold-catalyzed intermolecular addition of 1,3-dicarbonyl compounds to unactivated 1-alkynes (Nakamura reaction) is achieved at room temperature for the first time through synergistic gold/gallium catalysis. The developed system is highly efficient wit
