151007-74-8Relevant academic research and scientific papers
Transition-metal Complexes of Crown Ether Benzodithiolenes
Lowe, Nigel D.,Garner, C. David
, p. 2197 - 2208 (2007/10/02)
Three new dithiolene ligands have been synthesized, two of which have the novel feature of a crown ether ring attached directly to the benzene ring of an aryl dithiolene.Complexes with transition metals have been prepared and their (1)H, (13)C NMR, UV/VIS and electrochemical properties recorded.The information obtained appears to reflect variations in the degree of delocalisation in the metallodithiolene ring within the series of complex types.
