151007-80-6Relevant academic research and scientific papers
Oxidative addition chemistry of tetrathiocines: Synthesis, structures and properties of group 10 dithiolate complexes
Wrixon, Justin D.,Hayward, John J.,Raza, Osman,Rawson, Jeremy M.
, p. 2134 - 2139 (2014/01/17)
Oxidative addition of the electron-rich tetra-methoxy-dibenzo-1,2,5,6- tetrathiocine [(MeO)2C6H2S2] 2 to zero-valent group 10 transition metal complexes in the presence of diphenylphosphinoethane (dppe) affords the corresponding dithiolate complexes, [(DMOBD)M(dppe)] (DMOBD = dimethoxybenzenedithiolato, (MeO) 2C6H2S22-; M = Ni, Pd, Pt) in high yield which were characterized by single crystal X-ray diffraction. Whereas the Pd and Pt complexes exhibit two quasi-reversible 1e- oxidation processes, the nickel species undergoes a quasi-reversible 1e - reduction.
Transition-metal Complexes of Crown Ether Benzodithiolenes
Lowe, Nigel D.,Garner, C. David
, p. 2197 - 2208 (2007/10/02)
Three new dithiolene ligands have been synthesized, two of which have the novel feature of a crown ether ring attached directly to the benzene ring of an aryl dithiolene.Complexes with transition metals have been prepared and their (1)H, (13)C NMR, UV/VIS and electrochemical properties recorded.The information obtained appears to reflect variations in the degree of delocalisation in the metallodithiolene ring within the series of complex types.
