151071-00-0

Basic information

• Product Name: 4-BROMO-2-(3-METHYL-2-BUTENYL)-PHENOL
• Synonyms: 4-BROMO-2-(3-METHYL-2-BUTENYL)-PHENOL
• CAS NO: 151071-00-0
• Molecular Formula: C₁₁H₁₃BrO
• Molecular Weight: 241.12432
• Mol File: 151071-00-0.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 307.0±27.0 °C(Predicted)
• Appearance: /
• Density: 1.341±0.06 g/cm3(Predicted)
• PKA: 9.93±0.18(Predicted)
• CAS DataBase Reference: 4-BROMO-2-(3-METHYL-2-BUTENYL)-PHENOL(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BROMO-2-(3-METHYL-2-BUTENYL)-PHENOL(151071-00-0)
• EPA Substance Registry System: 4-BROMO-2-(3-METHYL-2-BUTENYL)-PHENOL(151071-00-0)

Safety Data

• Hazardous Substances Data: 151071-00-0(Hazardous Substances Data)

Upstream product

• 106-41-2 4-bromo-phenol 
• 115-18-4 2-methyl-3-buten-2-ol 
• 870-63-3 prenyl bromide 

Downstream Products

• 151071-01-1 4-bromo-2-(3-methyl-2-butenyl)phenyl acetate 
• 151071-02-2 methyl (E)-3-[4-(acetyloxy)-3-(3-methyl-2-butenyl)phenyl]-2-propenoate 
• 72704-01-9 (E)-methyl 3-[4-Hydroxy-3-(3-methylbut-2-en-1-yl)phenyl]acrylate 
• 259867-08-8 1-[2-(2-{2-{2-[2-(2-benzyloxycarbonylamino-acetylamino)-3-methyl-butyrylamino]-acetylamino}-3-hydroxy-3-[4-methoxy-3-(3-methyl-butyl)-phenyl]-propionylamino}-acetylamino)-3-(1H-indol-3-yl)-propionyl]-pyrrolidine-2-carboxylic acid benzyl ester 
• 259867-09-9 1-[2-(2-{2-{2-[2-(2-benzyloxycarbonylamino-acetylamino)-3-methyl-butyrylamino]-acetylamino}-3-hydroxy-3-[4-methoxy-3-(3-methyl-butyl)-phenyl]-propionylamino}-acetylamino)-3-(1H-indol-3-yl)-propionyl]-pyrrolidine-2-carboxylic acid benzyl ester 
• 259867-07-7 (2S,3R)-2-{2-[(S)-2-(2-Benzyloxycarbonylamino-acetylamino)-3-methyl-butyrylamino]-acetylamino}-3-hydroxy-3-[4-methoxy-3-(3-methyl-butyl)-phenyl]-propionic acid methyl ester 
• 259867-06-6 (2S,3S)-2-{2-[(S)-2-(2-Benzyloxycarbonylamino-acetylamino)-3-methyl-butyrylamino]-acetylamino}-3-hydroxy-3-[4-methoxy-3-(3-methyl-butyl)-phenyl]-propionic acid methyl ester 
• 259866-97-2 (S)-((2S,5R)-5-Isopropyl-3,6-dimethoxy-2,5-dihydro-pyrazin-2-yl)-[4-methoxy-3-(3-methyl-but-2-enyl)-phenyl]-methanol 
• 259867-00-0 (R)-((2S,5R)-5-Isopropyl-3,6-dimethoxy-2,5-dihydro-pyrazin-2-yl)-[4-methoxy-3-(3-methyl-but-2-enyl)-phenyl]-methanol 
• 259867-05-5 (2S,3R)-2-Amino-3-hydroxy-3-[4-methoxy-3-(3-methyl-but-2-enyl)-phenyl]-propionic acid methyl ester 
• 259867-04-4 (2S,3S)-2-Amino-3-hydroxy-3-[4-methoxy-3-(3-methyl-but-2-enyl)-phenyl]-propionic acid methyl ester 
• 259867-13-5 cyclic Pro-Gly-Val-Gly-Tyr(β-OH,4-methyl,3-(2-methylbutyl))-Gly-Trp 
• 56074-98-7 4-Methoxy-3-(γ,γ-dimethylallyl)benzaldehyde 

Relevant articles and documents

Chemical Synthesis Study Establishes the Correct Structure of the Potent Anti-Inflammatory Agent Myrsinoic Acid F

A total synthesis of compound 3 from p-bromophenol is reported and thereby establishing that this, rather than its cyclodehydrated counterpart 1 (as postulated originally), is the correct structure of the natural product myrsinoic acid F. The biological evaluation of compound 3 in a mouse-ear edema assay established that it is a significantly more potent anti-inflammatory agent than the NSAID indometacin.

Regioselectivity in the ene reaction of singlet oxygen with ortho-prenylphenol derivatives

The ene reaction of singlet oxygen with prenylated dihydroxyacetophenones led to the 2-hydroperoxy-3-methylbut-3-enyl derivatives as the major product. This original regioselectivity outlined a new effect, in competition with the previously established la

First syntheses of (2S,3S)- and (2S,3R) - m-prenyl-β-hydroxytyrosine derivatives: Bioactive amino acid fragment of a substance P antagonist novel cyclic heptapeptide

A stereodefined synthesis of both the C-3 isomers of the title tyrosine related new amino acid 3 has been achieved starting from D-serine and 4-bromophenol.