151071-10-2

Upstream product

• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 142012-05-3 (1R,2S,3R,4S)-4-butyryloxy-2,3-isopropylidenedioxy-5-cyclohexen-1-ol 

Downstream Products

• 156619-24-8 (1R,2R,3S,4R)-2,3-isopropylidenedioxy-4-(4-methoxybenzyloxy)-5-cyclohexen-1-ol 
• 151071-13-5 (1R,2R,3S,4R)-1-(t-butyldiphenylsilyloxy)-4-(4-methoxybenzyloxy)-2,3-sulfuryldioxy-5-cyclohexene 
• 151071-14-6 (1R,2R,3R,4R)-3-azido-1-(4-methoxybenzyloxy)-4-(t-butyldiphenylsilyloxy)-5-cyclohexen-2-ol 
• 151071-11-3 tert-Butyl-[(3aS,4R,7R,7aS)-7-(4-methoxy-benzyloxy)-2,2-dimethyl-3a,4,7,7a-tetrahydro-benzo[1,3]dioxol-4-yloxy]-diphenyl-silane 
• 151071-12-4 (1R,2S,3R,6R)-3-(tert-Butyl-diphenyl-silanyloxy)-6-(4-methoxy-benzyloxy)-cyclohex-4-ene-1,2-diol 
• 151071-19-1 (1R,2R,3S,4S,5R,6R)-4-azido-3,5-dibenzyloxy-2-methoxy-9-methyl-8-oxo-9-aza-7-oxabicyclo(4,3,0)-nonane 
• 151071-18-0 Methyl-carbamic acid (1S,2S,3R,4S,5S,6S)-4-azido-3,5-bis-benzyloxy-7-oxa-bicyclo[4.1.0]hept-2-yl ester 
• 151071-17-9 (1R,2S,3R,4R,5S,6S)-4-Azido-3,5-bis-benzyloxy-7-oxa-bicyclo[4.1.0]heptan-2-ol 
• 151071-16-8 (1S,2S,3R,4S,5S,6S)-2-azido-5,6-epoxy-4-(4-methoxybenzyloxy)-cyclohexan-1,3-diol 
• 72351-21-4 (+)-fortamine dihydrochloride 
• 161510-33-4 (1R,2R,3S,4R,5R)-5-t-(butyldimethylsiloxy)methyl-2,3-isopropylidenedioxy-4-p-methoxybenzyloxy-1-cyclohexanol 
• 156570-05-7 (1S,2R,3S,4R,5R)-5-(t-butyldimethylsiloxy)methyl-2,3-isopropylidenedioxy-4-p-methoxybenzyloxy-1-cyclohexanol 
• 156570-06-8 (3aS,6R,7R,7aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-7-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-benzo[1,3]dioxol-4-one 
• 156570-03-5 tert-Butyl-[(3aS,4R,5R,7aR)-4-(4-methoxy-benzyloxy)-2,2-dimethyl-3a,4,5,7a-tetrahydro-benzo[1,3]dioxol-5-ylmethoxy]-dimethyl-silane 

Relevant academic research and scientific papers

Cyclohexane polyols: Enantioselective synthesis of (+)-fortamine and of pseudosugars

(1R,2S,3R,4S)-4-butyryloxy-2,3-isopropylidenedioxy-5-cyclohexe n-1-ol (1) obtained upon enzymatic hydrolysis of the corresponding meso-dibutyrate 4b is a fully functionalized homochiral building block for the synthesis of cyclohexane polyols. Applications

Enantioselective synthesis of (+)-fortamine

(+)-Fortamine, the 1,4-diaminocyclitol aglycone of fortimicin antibiotics, has been achieved in a 15-step sequence from a previously described homochiral building block.