151075-88-6

Basic information

• Product Name: benzyl 2,3,4-tri-O-benzyl-6-O-trifluoromethanesulfonyl-β-D-glucopyranoside
• Synonyms: benzyl 2,3,4-tri-O-benzyl-6-O-trifluoromethanesulfonyl-β-D-glucopyranoside
• CAS NO: 151075-88-6
• Molecular Weight: 672.719
• Mol File: 151075-88-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: benzyl 2,3,4-tri-O-benzyl-6-O-trifluoromethanesulfonyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 2,3,4-tri-O-benzyl-6-O-trifluoromethanesulfonyl-β-D-glucopyranoside(151075-88-6)
• EPA Substance Registry System: benzyl 2,3,4-tri-O-benzyl-6-O-trifluoromethanesulfonyl-β-D-glucopyranoside(151075-88-6)

Safety Data

• Hazardous Substances Data: 151075-88-6(Hazardous Substances Data)

Upstream product

• 4304-12-5 (2R,3R,4S,5S,6R)-2-(benzyloxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol 
• 291527-97-4 benzyl 6-O-tert-butyldiphenylsilyl-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 291528-10-4 benzyl 6-O-tert-butyldiphenylsilyl-β-D-glucopyranoside 
• 27851-29-2 benzyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 358-23-6 trifluoromethylsulfonic anhydride 

Downstream Products

• 291527-98-5 benzyl 6-deoxy-6-(diethylphosphonomethyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 1286740-17-7 2-(1,1-difluoro-2-((2R,3R,4S,5R,6R)-3,4,5,6-tetrakis(benzyloxy)tetrahydro-2H-pyran-2-yl)ethylsulfonyl)pyridine 
• 1300116-21-5 2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-[(S)-(1,2,3,4-tetra-O-benzyl-6-deoxy-β-D-glucopyranos-6-yl)episulfoniumylidene]-D-arabinitol trifluoromethanesulfonate 
• 1053637-09-4 benzyl 6-deoxy-6-[diethylphosphono(1'-hydroxy)methyl]-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 789467-03-4 [1,1-Difluoro-2-((2R,3R,4S,5R,6R)-3,4,5,6-tetrakis-benzyloxy-tetrahydro-pyran-2-yl)-ethyl]-phosphonic acid 
• 291528-02-4 benzyl 6-deoxy-6-formyl-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 352439-10-2 benzyl 6-deoxy-6-[(diethylphosphono)-(S)-fluoromethyl]-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 352439-06-6 benzyl 6-deoxy-6-[(diethylphosphono)-(R)-fluoromethyl]-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 918900-76-2 benzyl 6-deoxy-6-[(isobutylsulfono)difluoromethyl]-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 918900-75-1 benzyl 6-deoxy-6-[(isobutylsulfono)fluoromethyl]-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 918900-85-3 benzyl 6-deoxy-6-[bis(2,4-dimethoxybenzyl)aminosulfonylmethyl]-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 918900-71-7 benzyl 6-deoxy-6-(neopentylsulfonomethyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 918900-74-0 benzyl 6-deoxy-6-(isobutylsulfonomethyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside 

Relevant articles and documents

Isolation, structure identification and SAR studies on thiosugar sulfonium salts, neosalaprinol and neoponkoranol, as potent α-glucosidase inhibitors

Two hitherto missing members of sulfonium salts family in Salacia genus plants as a new class of α-glucosidase inhibitors, neoponkoranol (7) and neosalaprinol (8), were isolated from the water extracts, and their structures were unambiguously identified.

Synthesis of (α,α-Difluoroalkyl)phosphonates by Displacement of Primary Triflates

Simple primary alkyl triflates and those derived from several monosaccharides are cleanly displaced by diethyl(lithiodifluoromethyl)phosphonate to provide the corresponding (α,α-difluoroalkyl)phosphonates in minutes at -78 deg C.