151122-97-3Relevant academic research and scientific papers
AN APPLICATION OF THE SUAREZ REACTION TO THE REGIOSPECIFIC AND STEREOSPECIFIC SYNTHESIS OF THE C28-C42 SEGMENT OF RAPAMYCIN
Hayward, Cheryl M.,Fisher, Matthew J.,Yohannes, Daniel,Danishefsky, Samuel J.
, p. 3989 - 3992 (2007/10/02)
Specific lactonization of a TBS ether followed by iodinative scission of a γ-lactol are the key elements of a strategy for maintaining continuous chemical distinction between the latent C34 and C32 hydroxyl groups of starting material 3 en route to 14, the C28-C42 fragment of rapamycin.
