1512-28-3Relevant academic research and scientific papers
Electronic structure of chiral halomethanes
Novak, Igor,Li, Dong Bo,Potts, Anthony W.
, p. 465 - 468 (2002)
The electronic structure of chiral halomethanes was studied for the analysis of intermolecular interactions. Their photoelectron spectra contain unanmbiguously assigned bands which acts as an internal probe for such interactions. The study of the electron
Novel synthetic approaches to CHBrFI, CHClFI and CHBrClI
Li, Dong Bo,Ng, Siu-Choon,Novak, Igor
, p. 5923 - 5926 (2002)
Three new facile methods for the preparations of racemic mixtures of CHBrFI, CHClFI and CHBrClI are described. Mercuric fluoride was found to be an effective fluorinating agent in fluorinations of CHI2Br(6) and CHI2Cl(8) to yield CHBrFI, CHClFI, respectively. Chlorination of CHI2Br(6) by using antimony pentachloride as a chlorinating agent, afforded CHBrClI in convenient and mild condition.
Chlorofluoroiodomethane as a potential candidate for parity violation measurements
Soulard, Pascale,Asselin, Pierre,Cuisset, Arnaud,Aviles Moreno, Juan Ramon,Huet, Therese R.,Petitprez, Denis,Demaison, Jean,Freedman, Teresa B.,Cao, Xiaolin,Nafie, Laurence A.,Crassous, Jeanne
, p. 79 - 92 (2008/02/12)
CHFClI is among the more favorable molecules for parity violation (PV) measurements in molecules. Despite the fact that calculated PV effects are two orders of magnitude smaller than in some organometallic compounds, CHFClI displays interesting features which could make possible a new experimental PV test on this molecule. Indeed, ultrahigh resolution spectroscopy using an ultrastable CO2 laser is favored by several intrinsic properties of this molecule. For example, the high vapor pressure of CHFClI allows investigation by supersonic beam spectroscopy. Indeed, the spectroscopic constants have been accurately determined by microwave and millimetre wave spectroscopy. This is important for the subsequent selection of an appropriate absorption band of CHFClI that could be brought to coincide with the absorption of CO2. Partially resolved (+)- and (-)-CHFClI enantiomers with respectively 63.3 and 20.5% ee's have been recently prepared and analyzed by molecular recognition using chiral hosts called cryptophanes. Finally, the S-(+)/R-(-) absolute configuration was ascertained by vibrational circular dichroism (VCD) in the gas phase. the Owner Societies 2006.
