15121-01-4

Basic information

• Product Name: 1-[7-Oxabicyclo[4.1.0]hept-1-yl]ethanone
• Synonyms: 1-[7-Oxabicyclo[4.1.0]hept-1-yl]ethanone;7-Oxabicyclo[4.1.0]hept-1-yl(methyl) ketone
• CAS NO: 15121-01-4
• Molecular Formula: C₈H₁₂O₂
• Molecular Weight: 140.18
• Mol File: 15121-01-4.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-[7-Oxabicyclo[4.1.0]hept-1-yl]ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[7-Oxabicyclo[4.1.0]hept-1-yl]ethanone(15121-01-4)
• EPA Substance Registry System: 1-[7-Oxabicyclo[4.1.0]hept-1-yl]ethanone(15121-01-4)

Safety Data

• Hazardous Substances Data: 15121-01-4(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthetic Communications, 19, p. 3579, 1989 DOI: 10.1080/00397918908052768

Upstream product

• 932-66-1 1-cyclohexenyl methyl ketone 

Downstream Products

• 63718-26-3 2-acetylcyclohexanol 
• 90112-22-4 2-ethylidene-cyclohexanol 
• 33830-26-1 trans-1-acetyl-2-hydroxycyclohexane 
• 127619-71-0 cis-1-acetyl-2-hydroxycyclohexane 
• 1122-25-4 2-ethylidenecyclohexan-1-one 
• 213996-67-9 1-[cis-3-N-(p-methoxyphenyl)aminoacryloyl]-1,2-epoxycyclohexane 
• 213996-66-8 1-[cis-3-N-(p-methylphenyl)aminoacryloyl]-1,2-epoxycyclohexane 
• 213996-65-7 1-(cis-3-N-phenylaminoacryloyl)-1,2-epoxycyclohexane 
• 699-41-2 1-(1,2-dihydroxycyclohexyl)ethanone 
• 699-41-2 (+/-)-1-(1,2t-dihydroxy-cyclohex-r-yl)-ethanone 

Relevant articles and documents

Effective aerobic allylic oxidation of β-ionone and series of olefins catalyzed by phosphomolybdic acid

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Rearrangement of acyloxyoxiranes: A revised structure for the oxidation product of 5α-androst-16-ene-3α,17-diol 3-benzoate 17-acetate

During the oxidation of conjugated enones to α-acyloxyoxiranes by m-chloroperbenzoic acid, the preferred sequence is epoxidation followed by Baeyer-Villiger oxidation. Rearrangement of acyloxyoxiranes to α-acyloxyketones, in situ, was observed. The α-keto

NEW DEVELOPMENTS OF THE WHARTON TRANSPOSITION

The synthetically useful Wharton transposition can be improved by using a more adequate procedure in the critical step of the intermediate α-epoxyhydrazone cleavage.Either for stable hydrazones or unstable ones, the yield of the transposed allylic alcohol is increased by treatment under anhydrous conditions with highly basic reagents (KDA in the former case, NEt3 in the latter).